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Lecturer(s)
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Herchel Radovan, doc. Ing. Ph.D.
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Drahoš Bohuslav, doc. RNDr. Ph.D.
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Štarha Pavel, doc. Mgr. Ph.D.
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Course content
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" basic terms of coordination chemistry - complex, coordination number, ligand, types of complexes, bonds in complexes, metal-metal bond, hydrogen bond, the valence bond theory, the theory of molecular orbitals, crystal field theory, ligand field theory, splitting of d-orbitals " introduction into transition metal chemistry - oxidation states, colour, magnetism, coordination geometry - stereochemistry, hybridization, secondary hybridization, isomerism, electronic spectra, magnetochemistry " general methods, which can be utilize for the preparation of complexes " complexes in solutions - determinations of constant stability , influences of solvents, non-water solutions, less common oxidation states "mixed-valence" complexes, the theory of acids and bases " kinetics and mechanism of reactions of transition metal complexes - substitution reactions, transfer-electron reactions, reactions of coordinated ligands " complexes with -acceptor ligands - carbonyls, cyano-complexes, nitrosyl-complexes, complexes with molecular nitrogen, clasters, -complexes - olefins, metallocens, "sandwich" complexes " organometallic complexes - methods for the preparation " homogeneous (Wilkinson's catalyst, hydrogenation, dimerization and izomerization of olefins, template synthesis) a heterogeneous catalyses (Fischer-Tropsch's process, Ziegler-Natta catalyst,..) " selected biological systems (bioinorganic chemistry), hemoglobine, hemocyanine, hemerythrine
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Learning activities and teaching methods
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Lecture
- Attendace
- 16 hours per semester
- Homework for Teaching
- 28 hours per semester
- Preparation for the Exam
- 16 hours per semester
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Learning outcomes
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The lecture introduces students to basic concepts of coordination chemistry and describes the properties of coordination compounds with emphasis on preparation, bonding possibilities, structure and reactions.
Describe properties of coordination compounds with the emphasis on magnetic and spectral properties, synthesis, bonding possibilities, structure, reactions and application in practice.
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Prerequisites
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unspecified
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Assessment methods and criteria
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Oral exam
Exam according syllabus.
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Recommended literature
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(1991). Modern Inorganic Chemistry. Second Edition, William L. Jolly, McGraw-Hill, Inc.
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Cotton, F. A., Wilkinson, A. G., et al. (1999). Advanced Inorganic Chemistry. Sixth Edition, John Wiley & Sons, Inc.
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F. A. Cotton, G. Wilkinson. (1973). Anorganická chemie. Academia, Praha.
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F. Březina, R. Pastorek. (1991). Koordinační chemie. UP, Olomouc.
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F. Kašpárek. (1993). Chemie organokovových sloučenin - 2. díl. Deriváty přechodných kovů. UP, Olomouc.
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F. Kašpárek. (1991). Chemie organokovových sloučenin. UP, Olomouc.
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Greenwood, N. N. a Earnshaw, A. (1993). Chemie prvků. Informatorium, Praha.
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Heslop, R. B., Jones, K. (1982). Anorganická chemie. SNTL, Praha.
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Inczédy, J. (1974). Komplexné rovnováhy v analytickej chémii. Alfa, Bratislava.
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Shiver, D. F. and Atkins, P. W. (1999). Inorganic Chemistry. Third Edition, Oxford University.
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von Zalewsky, A. (1994). Stereochemistry of Coordination Compounds. John Wiley.
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