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Lecturer(s)
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Course content
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" an introduction in molecular symmetry, -point groups, basics of matrix representations, the representation G3N, -Mulliken's symbols " free ion (elektron configuration, Russel-Saunders approach) " the ions in fields of nonspheric symmetry " an introduction to CFT, LFT, Tanabe-Sugano diagrams " electron spectroscopy of the transition metal complex compounds " magnetic properties of matter, magnetic susceptibility and measurement principles diamagnetism, magnetically dilute compounds, paramagnetism " spin-exchange, antiferromagnetism and ferrimagnetism " survey of the spectral and magnetic properties of the complex compounds of the 1. transition serie elements " electron paramagnetic resonance (EPR)- elemental introduction, description of the resonance experiment " photoelectron spectroscopy in coordination chemistry, XPS and UPS method " Mössbauer spectroscopy (in chemistry of iron) " ORD and circular dichroism (Cotton phenomenon) in coordination compounds study
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Learning activities and teaching methods
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Lecture
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Learning outcomes
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The lecture is focused on the basic theoretical ideas about the electron structure of complex compounds with the use of bases and LFT interpretation of spectral and magnetic properties of substances.
Recall basic principles of electron and vibration spectroscopy, basic methods of measurements and interpretation of magnetic properties of transition metal complex compounds. Elemental introduction to group theory and molecular symmetry their aplications in chemistry. Describe theory and experimental techniques of electron structure spectral methods study of coordination compounds.
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Prerequisites
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unspecified
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Assessment methods and criteria
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Oral exam
Oral exam (sayllabus extent).
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Recommended literature
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A. A. Vlček. (1966). Struktura a vlastnosti koordinačních sloučenin. ČSAV, Praha.
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A. B. P. Lever. (1984). Studies in physical and theoretical chemistry 33, Inorganic Electronic Spectroscopy. Sec. Ed. Elsevier.
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E. A. Boudroux, L. N. Mulay. (1976). Theory and applications of molecular paramagnetism. Wiley&Sons, New York.
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F. Březina a kolektiv. (1994). Stereochemie a některé fyzikálně chemické metody studia anorganických látek. UP, Olomouc.
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J. Fišer. (1980). Úvod do molekulové symetrie (Aplikace teorie grup v chemii). SNTL, Praha.
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P. Pelikán, R. Boča. (1987). Kvantová chémia koordinačných zlúčenín. Veda, Bratislava.
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V. Prosser. (1989). Experimentální metody biofyziky. Academia, Praha.
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