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Lecturer(s)
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Fryčák Petr, doc. RNDr. Ph.D.
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Course content
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Theoretical aspects of analytical chemistry cover the most important types of chemical reactions and equilibria involved in separation, detection and determination of compounds in solutions. Establishment of equilibrium conditions is explained on the basis of characterization of solution composition, knowledge of reaction mechanisms, and relationships between properties of compounds and reaction medium. The main themes: Thermodynamics and kinetics of chemical reactions, acid-base equilibria in aqueous and nonaqueous media, influence of relative permitivity and components of a medium on the strength of acids and bases, acidity scales in amphiprotic, aprotic and innert solvents, characterization and analytical application of colored protolytes (indicators), theory of complexation, precipitation and oxidation-reduction reactions, influence of media on equilibria in solution, methods for determination of equilibrium constants, distribution and quantification of components in equilibrium systems and their graphic representation.
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Learning activities and teaching methods
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Lecture
- Attendace
- 39 hours per semester
- Homework for Teaching
- 13 hours per semester
- Preparation for the Course Credit
- 38 hours per semester
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Learning outcomes
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The aim is to gain knowledge of theoretical aspects of analytical chemistry.
Classification of analytical reactions, analysis of side equilibria, calculation of concentrations of particular forms of a analyte present in solution.
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Prerequisites
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Successfully completed AC2 course.
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Assessment methods and criteria
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Oral exam
To demonstrate sufficient knowledge of the subject at the exam.
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Recommended literature
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Čermáková L., Němec I.: Vybrané kapitoly z teoretické analytické chemie. SPN Praha 1983..
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Harvey D.: Modern Analytical Chemistry. McGraw-Hill, New York 2000..
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Kellner R., Mermet J.-M., Otto M., Valcárcel M., Widmer, H. M.(eds.): Analytical Chemistry..
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Kotouček M., Skopalová J.: Příklady z analytické chemie. 4.vyd., UP Olomouc 1997..
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Kotouček M.: Teoretické aspekty analytické chemie, skriptum, PřF UP Olomouc 1989. Šůcha L., Kotrlý S.: Teoretické základy analytické chemie, SNTL, Praha 1971, resp. Solution Equilibria in Analytical Chemistry, Van Nostrand+Reinhold, London 1972. Čermáková L., Němec I.: Vybrané kapitoly teoretické analytické chemie, skriptum, Přírodovědecká fakulta UK Praha 1983. Kotouček M., Skopalová J.: Příklady z analytické chemie, skriptum, UP Olomouc 1997..
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Kotrlý S., Šůcha L.: Chemické rovnováhy v analytické chemii. SNTL Praha 1988..
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Šůcha L., Kotrlý S.: Solution Equilibria in Analytical Chemistry. Van Nostrand, London 1972..
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Šůcha L., Kotrlý S.: Teoretické základy analytické chemie. SNTL Praha 1971..
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