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Lecturer(s)
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Bárta Ondřej, Mgr. Ph.D.
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Drahoš Bohuslav, doc. RNDr. Ph.D.
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Course content
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" characterisation of organometallic compounds, carbon-metal bonding types. classification of organometallic compounds, organometallic compounds of transition metals-the most populated group " general properties of organometallic complexes, methods of preparation of organometallic compound with transtion and non-transition elements " reactions of organometallic compounds of non-transition elements, reaction with inorganic and organic molecules, reaction of carbonyls and their important derivatives " summary of organometallic compounds, ganometallics of alkali metals and second group elements (Grignard reagent), organometallic compounds of 13-15 groups of a periodic table (organoboranes, boron's a borin's acid ...) " organometallic compounds with mono-, di- tri and poly electron ligands (carbonyls, carbenes and carbynes, alkenes, cyklobutadienyl complexes, metallocenes) " reaction of organometallic compounds of transition metals, coordination of alkenes, substitution reactions, oxidation-reduction reactions, insertion reactions and reactions of coordinated ligands " organometallic polymers, their characterisation and properties, common types of organometallic compounds " clusters and the metal-metal bond, giant clusters and nanoparticles " methods of characterisation of organometallic compounds (1H, 13C, 31P NMR, IR spectroscopy, crystallography ...) " application of organometallic compounds in use, heterogeneous and homogenous catalysis, bioorganometallic chemistry.
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Learning activities and teaching methods
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Lecture
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Learning outcomes
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"Organometallic Compounds" lecture extend knowledge of inorganic chemistry and is focused on characterization of organometllic compounds and new possibilities their syntheses and applications. It is addressed to master's degree students of inorganic chemistry and also to student of chemistry teaching disciplines.
Describe the different type of organometalic compounds including clusters, their syntheses, their reaction with other simple molecules and possibility of their application especially in catalysis. Recall basic terminology from coordination chemistry: ligand, coordination number, geometry, etc.
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Prerequisites
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Successfully completed AGC2 or AGX2 courses.
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Assessment methods and criteria
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Written exam
Minimal successfulness in written tests must be at least 60%. In the case of lower percentage value the oral discussion about chosen problem.
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Recommended literature
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Crabtree, R. H. (2005). The organometallic chemistry of the transition metals. Fourth Edition, Wiley & Sons, New Persey.
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D. D. Archer. (2001). Inorganic and Organometallic Polymers. Wiley & Sons, New York.
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F. Kašpárek. (1993). Chemie organokovových sloučenin - 2. díl. Deriváty přechodných kovů. UP, Olomouc.
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F. Kašpárek. (1991). Chemie organokovových sloučenin. UP, Olomouc.
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Komiya, S. (1997). Synthesis of Organometallic Compounds. John Wiley & Sons, Chichester, 442 pp.
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