Division of separation methods . Separation according to the size of particles on the basis of various migration rate in a force field (sedimentation, centrifugation, ultracentrifugation, cyclones, impactors , foam flotation, thermodiffusion, electrostatic and magnetic separations, methods of flow analysis-FFF), permeation methods, ( sieving, filtration, membrane methods, ultrafiltration, dialysis, electrodialysis, reverse osmosis ). Physical-chemical separations ( chilling, crystallization, zonic crystallization, salt displacement and precipitation, inclusive compounds, sublimation, lyophilization, distillation and rectification-, azeotropic dislillation,co-distillation, vacuum distillation, molecular distillation). Selective dissolution, (L-S extraction). Liquid (L-S ) extraction ( deviations from distributive principle, extraction system of simple molecules, pseudomolecular substance, chelate complexes and ion ). Gas Chromatography: theory -Van Deemeterś equation and characteristic of individual terms , equations for capillary and packing columns, differentiation and its influencing, column selection. Sample injection system for packing and capillary columns, TCD, FID, AFID, (TID,NPD), HeD(ArD), CSD, ECD,PID detectors ,electrochemical detectors, O-FID, combined techniques (GC/AED,GC/MS,GC/FTIR). Quality in GC-retention data, retention indexes and their connections with a structure, selective detection, derivatization, reaction gas chromatography, ( abstraction techniques, hydrogenation, dehydrogenation, carbon skeleton chromatography , pyrolysis, identification reaction behind a column). Quantification of results in column methods.
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-
C.F. Poole. Gas Chromatography. Elsevier, Amsterdam 2012.
-
D. Harvey, The Mc Graw Hill 2000. Modern Analytical Chemistry.
-
D.A. Skoog a kol. Analytická chemie. VŠCHT, Praha 2019..
-
Ed. R.L. Grob, E.F. Barry. Modern Practice of Gas Chromatography, Wiley-Interssience , 2004.
-
J.Churáček a kol. Analytická separace látek, SNTL Praha, 1990..
-
Poole C. F., Poole S. K. Chromatography today, Elsevier, Amsterdam 1991.
-
R.L. Grob, E.F. Barry. Modern Practice of Gas Chromatography, John Wiley & Sons, Inc., Hoboken 2004..
-
Štulík K. a kol. Analytické separační metody, Karolinum UK Praha 2004.
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