|
Lecturer(s)
|
-
Lemr Karel, prof. RNDr. Ph.D.
-
Borovcová Lucie, Mgr. Ph.D.
|
|
Course content
|
Introduction to analytical chemistry. Definition of basic terms. Methods of chemical analysis, sample analysis. Basic measurements in analytical chemistry (mass and volume measurement). Evaluation of analytical results. General analysis procedure. Composition of solutions. Analytical reactions and their sensitivity. Chemical and phase equilibria in analytical chemistry. Protolytic equilibria (solvents, pH measurements and calculations, buffers, use). Complex-forming reactions and equilibria (complex formation, influence of secondary equilibria, use). Precipitation reactions and equilibria (utilization of the product of solubility, precipitation with sulfane and hydroxide, use). Oxidation-reduction reactions and equilibria (reduction potential, reversible redox reaction, use). Utilization of catalytic and induced reactions. Extraction equilibria, extraction conditions, ion exchangers, ion-exchange equilibria, examples of phase equilibrium applications. Sample collection and treatment. Qualitative chemical analysis. Group reactions of cations, group division. Group reactions of anions. Sample qualitative analysis procedure. Selective reactions, selected examples. Methods of quantitative chemical analysis. Gravimetry (examples of gravimetric determinations, electrogravimetry, thermogravimetry). Volumetry (basic substances and purity of chemicals, titration curves, indicators and their use). Acidimetry, alkalimetry, complexometric titrations, precipitation titrations, oxidation-reduction titrations (types of titration curves, indication of equivalence point, use). Analysis of organic compounds. Evidence and determination of elements by elementary analysis. Evidence and identification of major functional groups. Gas analysis. Selected practical applications of discussed analytical methods.
|
|
Learning activities and teaching methods
|
Lecture, Dialogic Lecture (Discussion, Dialog, Brainstorming)
- Attendace
- 26 hours per semester
- Homework for Teaching
- 13 hours per semester
- Preparation for the Course Credit
- 21 hours per semester
|
|
Learning outcomes
|
To acquaint students with basic principles of analytical chemistry, with selected methods of qualitative and quantitative chemical analysis.
To explain basic steps of analytical procedure, to evaluate possible pitfalls. To explain principles of selected analytical methods, to judge their applicability and to suggest a suitable procedure, to process and to evaluate data.
|
|
Prerequisites
|
The knowledge of basics of general, organic, anorganic, physical and analytical chemistry is recommended.
|
|
Assessment methods and criteria
|
Written exam
Student has to pass the written test (to reach 60% or more points).
|
|
Recommended literature
|
-
Bartoš M., Šrámková J., Staněk V. (2011). Analytická chemie. Univerzita Pardubice.
-
Bartoš, M., Šrámková, J., Staněk, V., Renger, F., Kalous, J. (2004). Analytická chemie I. Univerzita Pardubice.
-
Dostál V., Šimek J. (2000). Důkaz některých anorganických iontů analytickými reakcemi. UP Olomouc.
-
Christian G.D., Dasqupta P.K., Schug K.A. (2014). Analytical chemistry 7th. ed.. Wiley Hoboken.
-
Skoog D.A., West D.M.. (1999). Fundamentals of Analytical Chemistry 7th. ed.. Winston New York.
-
Sommer L. (1998). Základy analytické chemie I. II.. Vutium Brno.
-
Volka K. a kolektiv. (1997). Analytická chemie I. II.. VŠCHT Praha.
-
Záruba K. a kolektiv. (2016). Analytická chemie (1.díl). VŠCHT Praha.
|